For any sets ‘A’ and ‘B’ there exists a set C={A,B} that contains exactly ‘A’ and ‘B’.
For the special case where A=B, C={A}, therefore, {A} exists.
Appendix A:
It is intriguing, why did we have a need to postulate the existence of a set with two sets?
Well, we may have found later why this postulate must be postulated: when working with Axiom of Foundation we need the existence of nonempty set A to imply the existence of {A}.
Since A is nonempty, we’re going to write A = {a} with element ‘a’ being whatever it is. The existence of this A means {{a}} exists, because {A}={{a}}.